Electrooxidation of organic compounds using some principles of green chemistry
نویسندگان
چکیده
It has been shown that ruthenium polypyridyl aqua complexes have basically the same electrochemical behavior in weakly coordinating organic solvents, such as methylene chloride and acetone, water. Therefore, their use electrocatalytic processes water, they conducted an ecologically cleaner system, can bring significant benefits for mankind, well nature economy. In this sense, new complex containing diphosphine polypyriridine ligands, [Ru(L)(totpy)(OH2)](ClO4)2 (L=Ph2PCH2CH2PPh2); (totpy=4´-(4-tolyl)-2,2´:6´,2´´-tripyridine), was used catalyst at pH 8.1 homogeneous electrooxidation of benzyl alcohol, benzaldehyde, benzylbutyl ether 1-phenylethanol.
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PREFACE N o period in the history of organic chemistry has been as dynamic and productive of research accomplishment as the twelve years between the completion of the first and present editions of this textbook. New reagents, new reactions, and extraordinary syntheses have been manifold. New techniques and new instruments for analysis and determination of structures, improved methods for theore...
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ژورنال
عنوان ژورنال: Disciplinarum Scientia
سال: 2023
ISSN: ['1981-2841', '2176-462X']
DOI: https://doi.org/10.37779/nt.v24i1.4461